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IIT JEE Chemistry Of Hydrocarbons Part 1
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1. Olafins means
ethene
unsaturated
oil forming
having tripple bond
2. Which of the following has dipole moment?
trans-2-butene
1-propene
cis-2-butene
Both A and B
3. In which of the following C-H bond will be smallest?
Ethylene
Acetylene
Methane
Ethane
4. Alkynes when reduced with sodium in liquid ammonia gives
1-alkene only
a mixture of cis and trans
alkenes
None of them
5. 12-butyne when reduced with palladised charcoal with poisons like quinoline gives
1-butene
butane
trans-2 butene
cis 2-butene
6. Vapours of ethyl alcohol when passed over phosphoric acid at 220 degreeCentigrade gives
diethyl phosphate
methylene
ethyl hydrogen phosphate
ethylene
7. Which of the following have maximum boiling point?
n-pentane
isopentane
isohexane
n-hexane
8. The reactivity of a hydrogen in an alkane depends on carbon atoms
conditions
carbon atoms
the alkane in which it is present
whether the hydrogen is primary secondary or tertiary
9. The addition reaction of carbon-carbon double bonds are free radical addition None of the above
nucleophilic addition
free radical addition
electrophilic addition
None of the above
10. With the increase in branching the boiling point
decreases
increases
no regular gradation
remains constant
11. Which of the following has minimum boiling point? isopentane both A and B
isopentane
neopentane
n-pentane
both A and B
12. Which of the following will show maximum possible isomers?
Pentene
Pentane
Butane
Butene
13. Propane when treated with conc. Nitric acid at 723 K gives
2-nitropropane
1-nitropropane
a mixture of nitromethane nitroethane 1-
a mixture of nitromethane nitroethane 1-nitropropane and 2-nitropropane nitroethane and nitromethane
14. Vapours of n-hexane when passed over special catalysts under high pressure and temperature given benzene This process is called
cyclisation
aromatisation
isomerisation
crystallization
15. Which of the following can form metallic derivatives by the replacement of hydrogen atoms? Ethylene
Ethylene
Acetylene
Ethane
Methane
16. Alkenes are isomeric with
cycloalkenes
cycloalkanes
alkanes
alkenes
17. The higher fraction of crude oil burn with pinkish flame
smokiest flame
pinkish flame
blue flame
red flame
18. Which of the following alkanes will undergo oxidation readily?
ethane
iso-butane
iso-pentane
2 methyl propane
19. A mixture of 1-chloropropane and 2-chloropropane is treated with alcoholic KOH. The resulting mixture will have
1-propene
2-propene
1-propanol
a mixture of 1-propene and 2-propene
20. On ozonolysis and subsequent hydrolysis an alkene gave 2 molecules of formaldehyde and hydrogen peroxide. The alkene is
ethylene
butylene
propylene
None of these
21. Wurtz reaction cannot be used for the preparation of
alkanes containing odd no. of C-atoms
alkanes containing even no. of C-atoms
methane
both methane and odd no. of C-atoms
22. Ethylene when treated with bromine water gives
ethyledene bromide
ethylene bromohydrin
ethylene bromide
methanol
23. Bromination of isobutene gives as major product
n-butyl bromide
tert. butyl bromide
isobutyl bromide
None of the above
24. Among the alkanes with an increase in mol wt??.
m.pt. decreases
f.pt. decreases
b.pt increases
density decreases
25. Alkyl halides gives alkenes when treated with
alc KOH
aq KOH
molten KOH
All the above
26. Tetraethyl lead is used as
petroleum additive
ethylating agent
antrepeller
catalyst
27. isomers of butyl chloride which will undergo dehydrogenation more readily
Among the different
tert. butyl chloride
sec. butyl chloride
n-butyl chloride
28. The least substituted alkene is the major product in accordance with
Vant Hoff rule
Wurtz reaction
Markounikoffs rule
Hoffmanns rule
29. Alcohholic solution of caustic potash is a specific reagent for
Dehydration
Dehydrohalogenation
Dehydrogenation
Hydration.
30. An example of conjugate diene is
hexadiene 1 5
butadiene 1 2
butadiene 1 3
pentadiene 1 4
31. Octane number of iso-octane is
Zero
100
80
20
32. In ethane each carbon atom is bonded to
4 atoms
2atoms
3 atoms
5 atoms
33. When two alkenes may be formed by dehydrohalogenation of an alkyl halide the alkene which is more substituted is the major or preferred product. This generalisation is known as .
Markownikoffs rule
Anti-Markownikoffs rule
Saytzeff rule
None of these is correct
34. To increase the yield of gasoline from a given sample of crude oil the chemist carries out
Fractiomal distillatiom
Hydrolysis
Aromatization
Cracking.
35. Polythene is a polymer of
ethylene
propylene
isobutene
vinyl chloride
36. Dehydrohalogenation of alkyl dihalides gives
alkyl halides
alkynes
alkenes
alkanes
37. The formation of PVC from vinyl chloride is an example of
condensation polymerisation
addition polymerisation
substitution reaction
None of these
38. Cetane is
n-Hexane
n-Octane
n-Pentadecane
n-Hexadecane.
39. Iodoform can be prepared in the laboratory by the action of iodine on sodium hydroxide in the presence of
formaldehyde
acetaldehyde
acetic acid
formic acid
40. Crude oil is a complex mixture of
acids
alcohols
hydrocarbons
esters
41. The number of isomeric pentanes is
4
3
2
1
42. During distillation of coal tar naphthalene is a constituent of
Middle oil
Green oil
Light oil
Heavy oil.
43. Alcoholic solution of caustic potash is a specific reagent for
dehydro-halogenation
dehydrogenation
dehydration
hydration
44. Aromatisation is the conversion of
higher hydrocarbon to lower ones
mixing of aromatic hydrocarbon
a hydrocarbon to benzene
None of above
45. Sodium propionate on decarboxylation with soda-lime gives
Propane
Ethane
Butane
Pentane.
46. Acetylene can be converted into methyl vinyl ether on reaction with
Vinyl alcohol
Methyl alcohol
Dimethyl ether
Methanal.
47. A mixture of sodium butanoate and 2-methyl sodium propanoate is heated with sodalime. The resulting compound will be
propane and propyne
a mixture of propane and 2-methyl propane
methane
propane
48. The minimum temp. at which oil gives sufficient vapours to form an explosive mixture with air is known as
optimum temp.
kindling temp.
flash point
last point
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