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IIT JEE Chemistry Of Hydrocarbons Part 2
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1. Acetylene can be converted into methyl vinyl ether on reaction with
Vinyl alcohol
Methyl alcohol
Dimethyl ether
Methanal.
2. A mixture of sodium butanoate and 2-methyl sodium propanoate is heated with sodalime. The resulting compound will be methane
propane and propyne
a mixture of propane and 2-methyl propane
methane
propane
3. The minimum temp. at which oil gives sufficient vapours to form an explosive mixture with air is known as last point
optimum temp.
kindling temp.
flash point
last point
4. A fuel having high octane number containing mainly
branched hydrocarbons
straight chain alkane
alkanes
All the above
5. Propyne on reaction with aqueous chlorine gives
1, 1, 2, 2-Tetrachloropropane
1, 2-Dichloropropene
1, 1-Dichloropropanone
2, 2-dichloropropanal.
6. he number of litres of air needed to burn completely 8 litres of acetylene is 100 75 90 40
100
75
90
40
7. Which of the following is most acidic ?
Ethyne
Propyne
1-Butyne
2-Butyne.
8. Electrolysis of potassium ethanoate gives
methane
propene
ethane
ethyne
9. .Which of the following is linear?
Ethyne
Methane
Ethylene
Both A and C
10. .Starting from benzene, toluene is prepared by
Reimer-Tiemann reaction
Friedel-Crafts acylation
Cannizzaros reaction
Kolbes reaction
11. .The ozonolysis is used to locate the presence of
a single bond between C-C atoms
a double bond between C-C atoms
a triple bond between C and C atoms
None of these
12. .Gas oil is the same as
diesel oil
petrol
kerosene oil
lubricating oil
13. Benzene reacts with excess of cholrine in sunlight to form Hexachlorobenzene
Hexachlorobenzene
m-Dichlorobenzene
Chlorobenzene
Benzene hexzchlorode.
14. Which of the following can form metallic derivatives by replacement of H-atoms ?
Ethene
Methane
2-Butyne
1-Pentyne.
15. When HCl is passed through propene in the presence of benzoyl peroxide, it gives
n-Propyl chloride
iso-Propyl chloride
Allyl chloride
No reaction.
16. 2, 3-Dibromobutane, when heat with zinc dust, yields .
2-Butene
2-Butyne
1-Butene
Butane
17. An example of conjugated diene is
1, 4-Pentadiene
1, 5-Hexadiene
1, 2-Butadiene
1, 3-Pentadiene.
18. .Which of the following compounds has the highest boiling point?
n-Hexane
n-Pentane
2, 2-Dimethylpropane
2-Methylbutane
19. Allylic bromination of an olefin is
Nucleophilic substitution
Electrophilic substitution
Free radical substitution
Electrophilic addition.
20. Addition of HCl to vinyl chloride gives 1, 1-dichlorocthane because of None of these.
Inductive effect of Cl
Mesomeric effect of Cl
Restricted rotation around double bond
None of these.
21. Gasoline contains hydrocarbons in the rane C-7 to C-12
C-7 to C-12
C-12 to C-15
C-4 to C-6
C-5 to C-8.
22. Which one of the following has the smallest heat of hydrogenation per mole? cis-2Butene
1-butene
trans-2-Butene
cis-2Butene
1, 3-Buteadiene.
23. Propene + HBr gives
1, 3-Dibromopropane
2-Bromopropane
1-Bromo propane
1, 2-Dibromopropane.
24. Which of the following is most acidic ? Methane Ethylene .
Methane
Ehtane
Ethylene
Acatylene
25. Which of the following derivatives of benzene would undergo nitration most readily?
Nitrobenzene
Chlorobenzene
Toluene
Benzoic acid.
26. Alkanes mainly show reactions having
Free radical formation
Ionic elimination
Ionic formation
Heat/photochemical substitution.
27. .see-Butyl chloride on boiling with alc. KOH gives ......... as the main product.
1-Butene
2-Butene
1-Butanol
2-Butanol.
28. .Isopropyl bromide on Wurtz reaction gives
Hexane
Propane
2, 3--Dimethylbutane
Neohexane.
29. The catalyst used in the manufacture of polyethene by Ziegler method is
Titanium tetrachloride and triphenyl aluminium
Titanium tetrachloride and trimethyl aluminimum
Titanium dioxide
Titanium isopropoxide.
30. Ozonolysis of p-xylene gives
Glyoxal
Methyl glyoxal
Both of these
None of these.
31. Aqueous sulphuric acid reacts with 2-methyl-1-butene to give predominantly
iso-Butyl hydrogen sulphate
2-Metyl-2-butanol
2-Methyl-1-butanol
sec-Butyl hydrogen sulphate.
32. When HBr adds to 1-butene in the presence of benzoyl peroxide, the product is
1-Bromobutane
2-Buromobutane
1-Bromobutene
2-Bromobutene.
33. On chlorination, nitrobenzene gives ........ as the major product.
o-Chloro nitrobenzene
p-chloro nitrobenzene
m-chloro nitrobenzene
All the three.
34. Towards electrophilic substitution the most reactive will be
Nitrobenzene
Aniline
Aniline hydrochloride
N-Acetylaniline.
35. Which of the following is least acidic ?
Ethyne
Propyne
1-Butyne
2-Butyne.
36. .Which of the following hydrocarbons would give a red precipitate on treatment with ammonical cuprous chloride solution ?
2-Butene
2-Butyne
1, 3-Butadiene
1-Butyne.
37. The addition of HBr to styrene gives ..... as the major product. 1-Bromo-1-phenylethane
1-Bromo-1-phenylethane
2-Bromo-1phenylethane
Benzyl chloride
p-Bromophentl ethylene.
38. Halogenation of alkanes is an example of .
Electrophilic substitution
Nucleopholic substitution
Free radical substitution
Reduction
39. To prepare a pure sample of n-hexane using sodium metal as one reactant, the other reactant will be
Ethyl chloride and n-butyl chloride
Methyl chloride and n-pentyl bromide
Ethyl bromide and n-bytyl bromide
n-Propyl bromide.
40. Sulphur monochloride reacts with .... to give mustard gas.
Eathane
Ethene
Ethyne
Methane.
41. Mesitylene can be obtained by polymerization of Ethyne
Ethyne
Ethene
Propene
Propyne.
42. Starting from which of the following compounds methane as well as ethane can be prepared in separate single steps ?
Ethyl magnesium bromide
Methyl bromide
Sodium propanoate
Ethyl alcohol.
43. Starting from which of t efollowing compounds can methane be prepared in one step ? All of these.
Sodium acetate
Aluminium carbide
Methyl magnesium bromide
All of these.
44. Benzene on ozonolysis yields
Glyoxal
Acetone
Ethanal
Methanal.
45. Among the following, the compound that can be most readily sulphonated is
Nitrobenzene
1, 3-Dinitrobenzene
Chlorobenzene
Toluene.
46. Ethyne can be prepared in a single step from
Calcium carbide
Ethylidene bromide
Ethylene bromide
All of these.
47. 1, 1-Dibromoethane when heated with zinc dust produces
Ethyl bromide
Ethene
Vinyl bromide
2-Butene.
48. Addition of HBr to iso-butylene mainly gives
iso-Butyl bromide
n-Butyl bromide
tert-Butyl bromide
sec-Butyl bromide.
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